Hestia is co-leader of Team Nasci (the name means 'to be born' 'to arise'), another team of legendary pokemon who, being only fresmen, aren't legendary yet.
Hestia has beauty, brains, and enough wealth to buy the academy, tear it down, and rebuild it. Despite this she isn't spoiled - her parents died quit tragically and she has never quite gotten over it. She has little control over her fortune - that being given to her guardian Jasi who has raised her.
Hestia has an on-again off-again relationship with Proteus from Team Aves. Ever since they were attacked by bullies before completing their first official kiss. She has not quite gotten over that yet either, though she has since dedicated herself to finding ways to stop bullies. She plans to be a business executive when she graduates, using her fortune to help solve the problems of the world.